![]() ![]() Our editors thoroughly review and fact-check every article to ensure that our content meets the highest standards. Our goal is to deliver the most accurate information and the most knowledgeable advice possible in order to help you make smarter buying decisions on tech gear and a wide array of products and services. ZDNet's editorial team writes on behalf of YOU, our reader. Indeed, we follow strict guidelines that ensure our editorial content is never influenced by advertisers. Neither ZDNet nor the author are compensated for these independent reviews. This helps support our work, but does not affect what we cover or how, and it does not affect the price you pay. When you click through from our site to a retailer and buy a product or service, we may earn affiliate commissions. And we pore over customer reviews to find out what matters to real people who already own and use the products and services we’re assessing. We gather data from the best available sources, including vendor and retailer listings as well as other relevant and independent reviews sites. ZDNet’s recommendations are based on many hours of testing, research, and comparison shopping. GET THIS you wont be sorry!! Just make sure you have a good graphics card.‘ZDNet Recommends’ What exactly does that mean? Great colors, deep blacks, very little light leakage(all lcds have some) no light leakage patches, very even. ![]() THIS LG has the LOWEST INPUT LAG OF ANY 24 inch lcd monitor. Monitor CAN be used at some non native resolutions if you dont like small text at native. Overall Review: If you are in the market for a 24 inch LCD this is the one to buy, great for gaming, BF2 and other new games, you'll need a good graphics card though. Considered several others before buying, very happy with my purchase of the LG, using the SRGB setting and 30 brightness everything looks great to me, very little fiddling with settings to get a great picture.Ĭons: I purchased an aftermarket DVI to HDMI cable as the cable that came with the monitor isnt shielded very well. Has the same PMVA panel as the Benq without all the problems of the Benq monitor. It is by far the best 24 inch lcd currently available. Pros: After careful research I picked this monitor up locally. Picture-In-Picture / Picture-By-Picture Functionĭimensions & Weight Dimensions (H x W x D)Īdditional Information Date First Available Intelligent Auto (Resolution) Control Function UL(cUL), TUV-GS, SEMKO, FCC-B, CE, TCO'99 Learn more about the LG Electronics L245WP-BN Model Brand Maximize your Windows Vista view with the impressive LG L245WP-BN display! Windows Vista CertifiedThe LG L245WP-BN display has passed the Windows Hardware Quality Labs testing for guaranteed compatibility with Windows Vista Premium standards.Four-way Adjustable StandThe LG L245WP-BN offers an ergonomic four-way adjustable stand: height, swivel, tilt and pivot for greatly increased comfort, efficiency and flexibility.Impressive ViewabilityThe LG L245WP-BN offers an ultra-wide 178° viewing angle both horizontally and vertically to ensure a perfect viewing experience from all orientations.HDMI’s appeal has made it the choice interface for a broad selection of HD-capable video devices and gaming consoles. HDMI InputThe LG L245WP-BN features an HDMI input to receive high-definition digital video and audio through a single, convenient cable connection.The 16:10 widescreen aspect ratio provides a truly broad window for superior viewing comfort and total HDTV movie and game immersion. HDTV-Ready WidescreenThe 24-inch LG L245WP-BN is fully HDTV-ready with a resolution of 1920x1200 supporting up to the 1080p (1920 x 1080, progressive) high definition format.It constantly makes image adjustments to photos, videos and games for spectacular looking images and enhanced viewing experiences. Flatron f-ENGINE TechnologyThe LG F-Engine is the industry’s first picture-quality enhancement chip. ![]()
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![]() ![]() Brighton Music Hall presented by Citizens Bank, Boston, MA. This title is a cover of Best Friend as made famous by Brandy. Listen to Best Friend by Brandy, 208,007 Shazams, featuring on Hip-Hop/R&B Throwback, and ’90s R&B Essentials Apple Music playlists. To keep me going strong, what else can I say, Friends are there through thick and thin You can also use the lyrics scroller to sing along with the … Times that you may think that you need a friend more », Brandy (from brandywine, derived from Dutch brandewijn-"burnt wine") is a spirit produced by distilling wine. "Best Friend" is a dance song with urban and R&B influences by American singer Brandy. ![]() Cuz I'm your sister, and always for ya, Don't know what I'd ever do without ya Whenever I'm down & all thats going on Repeat 1 (2x). Whenever I'm down, I call on you my friend A helping hand you lend, in my time of need so I I'm calling you now, just to make it through What else can I do, don't you hear my please Friends may come and friends may go Friends may come and friends may go. ![]() Friends may come and friends may go The song released as the album's third single in June 1995 (see 1995 in music). Brandy performed the song on Soul Train (1994) and Showtime at the Apollo (October 1995). It does not store any personal data.Best friend lyrics brandy. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. The cookie is used to store the user consent for the cookies in the category "Performance". This cookie is set by GDPR Cookie Consent plugin. The cookies is used to store the user consent for the cookies in the category "Necessary". The cookie is used to store the user consent for the cookies in the category "Other. The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The cookie is used to store the user consent for the cookies in the category "Analytics". These cookies ensure basic functionalities and security features of the website, anonymously. Necessary cookies are absolutely essential for the website to function properly. (You could take the full 2,200, but ideally you want to hook ’em with your pithy lede.) Whether it’s for a birthday, National Best Friends Day, or no specific reason at all, here are the best BFF songs lyrics to bring you inspo for captioning your Instagram post dedicated to your bestie. Or maybe you’re just scheming to build an Instagram shrine in honor of your forever friend, your perfect pal, the Serena to your Blair, the Nick Miller to your Schmidt, the Sam to your Carly, the Leslie Knope to your Ann Perkins.Īll-consuming love, be it romantic or platonic, can be a tricky thing to fit into words - especially when you’re trying to wedge those sentiments into the handful of characters that fit in an acceptable Instagram caption. Perhaps you corral your whole crew to a bottomless brunch, private karaoke room, or the beach for a long weekend. Maybe you’re the kind of friend who treats their BFF to a charcuterie picnic in a beautiful park and sets up comfortable chairs to bask in the sunlight together. We all love our besties and want to celebrate them, even if we don’t remind them as often as we should. ![]() ![]() ![]() Thiscompletely new landmark text is intended to bridge that gap. Contemporary chemists mustbe just as familiar with these newer fields as with the more establishedclassical topics. In the latter part of the 20th century, the field of physical organicchemistry went through dramatic changes, with an increased emphasis onnoncovalent interactions and their roles in molecular recognition,supramolecular chemistry, and biology the development of new materials with novel structural features and the use of computationalmethods. Thisis the first modern textbook, written in the 21st century, to makeexplicit the many connections between physical organic chemistry and criticalfields such as organometallic chemistry, materials chemistry, bioorganicchemistry, and biochemistry.(2000), 33(10), 658-664.Ī wonderful primer dealing with cyclic voltammetry (thermodynamic redox potentials E’s of HOMO (oxidation) and LUMO (reduction) photoelectron spectroscopy (PES Koopman’s theorem orbital energies for bound electrons) Do Secondary Orbital Interactions Really Exist? Acc. Direct Evaluation of Secondary Orbital Interactions in the Diels-Alder Reaction between Cyclopentadiene and Maleic Anhydride. Secondary orbital interactions Arrieta, Ana Cossio, Fernando P. Orbital energy control of cycloaddition reactivity. Substituent effects in Diels-Alder additions. Dewar’s original reference) Potential energy surfaces Textbook dealing with FMO theory - including some of the qualitative issues discussed in class today(10/24) re the polarization of MO’s as well as the Salem-Klopman equation “Frontier Orbitals and Organic Chemical Reactions”, Ian Fleming, Wiley ISBN (paperback) 0471018198 ln(k) vs HOMO/LUMO energy gap MO theory related Hückel MO theory - calculator qualitative MO theory AM1 (= Austin method 1) calculation method (M.J.S. A-values (conformational analysis - cyclohexanes) drawing cyclohexane Beak) Marcus equations – derivation & electron transfer Ĭonformational analysis Conformational analysis – a video featuring Nobel Laureate Sir Derek Barton Acyclic conformational analysis: _1/Lecture_4.pdf _2/Lecture_5.pdf Conformational analysis of cyclic systems: e_6.pdf e_07.pdf Chapter 18 (conformational analysis … see, also, the web sites), chapter 21 (formation of enols and enolates), and pages 898-900 (Zimmerman-Traxler transition states). Additional Curtin-Hammett references include, inter alia, Duan & Moeller, JACS, 2002, 124, 9368 modynamics.pdf nciple.shtml Bell-Evans-Polanyi (BEP) principle microscopic reversibility page 1105 of Clayden text and 139-143 reactivity-selectivity principle Dynamic thermodynamic resolution (P. Evaluations, applications, and extensions of Curtin-Hammett Winstein-Holness kinetics. Effect of conformational change on reactivity in organic chemistry. Analytical solution to the Curtin-Hammett/Winstein-Holness kinetic system. ![]() Hammond’s original reference) tml Curtin-Hammett principle Generalized discussion – Zefirov, N. kinetics vs thermodynamic control modynamics.pdf Arrhenius calculation - calculator Eyring and Arrhenius equations See: It’s a stand-alone text that meant to be covered in a full year course it is wellworth having on your bookshelf. Reich (U WI) (and associated links) and, from the University of Aberdeen, kinetics - thermodynamics reaction kinetics your text by Clayden, etal, as well as chapters 7 & 8 of “Modern Physical Organic Chemistry” by Dougherty and Anslyn University Science Books, copyright 2006 (available now. Important conference in the field phys org Gordon conference summer of 2005 Įlectron pushing – from Prof. Terms used in ‘the field’ glossary of terms used in physical organic chemistry IUPAC phys org Wentrup, WileyInterscience, 1984 Historical views and perspective on the field Streitweiser’s views on physical organic chemistry Hammond’s views Carpenter, Wiley Interscience, 1984 “Reactive Molecules, The Neutral Reactive Intermediates in Organic Chemistry”, C. Texts dealing with physical organic chemistry “Modern Physical Organic Chemistry”, Anslyn and Dougherty, University Science Books, 2006 (“Determination of Organic Reaction Mechanisms, B. ![]() ![]() ![]() We are continuing our efforts to vaccinate all our children 12 to 17 years and providing booster doses to front liners and vulnerable persons. It should be noted that South African states are poorly vaccinated compared to Fiji, and all our COVID safe measures are proven to work in reducing transmission especially within a highly vaccinated population. Current vaccines remain effective against severe disease and death. In this instance the current steps we are taking do not change we work on better positioning ourselves to deal with a third wave, irrespective of whether it is through Omicron or the current Delta variant that is endemic to Fiji.Įffectiveness of vaccines: While there is ongoing effort to understand the impact of this variant on vaccines, it is important to understand that vaccines remain critical to reducing severe disease and death, including against the dominant circulating variant, Delta. The public is advised that if indeed the virus is more transmissible than delta, then it will be inevitable that it gets to Fiji. There is some reported field evidence of increased transmissibility in South Africa however epidemiologic studies are underway to understand if it is because of Omicron or other factors. Transmissibility: It is not yet clear whether Omicron is more transmissible (e.g., more easily spread from person to person) compared to other variants, including Delta. Based on advice from the World Health Organization released today, we note the following: The Ministry of Health and Medical Services has continued to review findings released by international experts on the Omicron variant of the COVID-19 virus. 3,500 tests per week) and we anticipate continued surveillance and testing in our communities and maritime islands to monitor and detect cases for early intervention. ![]() Our weekly testing numbers of over 4,000 are still above the WHO recommended rate of 4 tests per 1,000 population per week (or approx. Our border health measures and surveillance will need to be strengthened and maintained. With increasing COVID-19 cases in the European region, and the emergence of the new variant of concern B.1.1.529, named Omicron, noted to have several mutations, is a cause for concern. With borders opening in the next two days, we anticipate our testing numbers to increase from international repatriates and travelers including Fijians visiting families and friends. With the commencement of vaccination for 12-14-year-olds, we expect their coverage to contribute to reducing the risk of severe disease, hospitalization, and death. Occupancy rates in health facilities, the occupancy rate of ICU beds, death rates, and vaccination coverage are indicators to monitor our health response capacity and we see a decreasing trend across indicators from our health facilities with increasing vaccination coverage for adults and 15-17-year-olds in Fiji. The Ministry of Health continues to monitor the outbreak using indicators such as daily case numbers, hospitalizations, test positivity, and deaths. We have recorded 604 COVID-19 positive patients who died from serious medical conditions they had before they contracted COVID-19 these are not classified as COVID-19 deaths. Therefore, as of November 25th, the national 7 days rolling average for COVID-19 deaths per day is 0.0, with a case fatality rate of 1.32%. Please note that due to the time required by clinical teams to investigate, classify and report deaths, a 4-day interval is given to calculate the 7 days rolling average of deaths, based on the date of death, to help ensure the data collected is complete before the average is reported. There have been a total of 696 deaths due to COVID-19 in Fiji, with 694 of these deaths during the outbreak that started in April this year. The differences between the Central and Western are similar to the incidence of the daily cases and are likely a reflection of vaccination levels, COVID mitigation measures, and differences in population density. Overall, the death rate graphs for the Central and Western Divisions indicate a declining trend. This curve depicts the daily death count by division since the 2nd wave of this outbreak began in April 2021. Our National 7- day rolling average is 7 daily cases calculated for 25th November 2021. ![]() Overall, for this 2nd wave, there have been 52,436 cases recorded, with 71% of the cases from the Central Division, 28% of the cases from the Western Division, and 1% of the cases from the Eastern and Northern Division. This epidemic curve depicts the daily positive cases since the 2nd wave of this outbreak that began in April 2021. Since the last update, we have recorded a total of 12 new cases of which 4 new cases were recorded on, 8 new cases were recorded on, and nil new cases in the last 24 hours ending at 8 am this morning. Last Updated on 3 days by Publishing Team ![]() ![]() ![]()
![]() ![]() Cétautomatix (Fulliautomatix) - Gaulish village smith.Ordralfabétix (Unhygienix) - Gaulish village fishmonger.Agecanonix (Geriatrix) - Oldest living member of the Gaulish village.Assurancetourix (Caconofix) - Gaulish village bard.Bonemine (Impedimenta) - Wife of the village chief.Abraracourcix (Vitalstatistix) - Gaulish village chief.Panoramix (Getafix) - Gaulish village druid who holds the secret to the 'magic potion' which makes the drinker invincible.Obélix (Obelix) - Sidekick, Gaulish menhir delivery man.Astérix (Asterix) - Main hero, Gaulish warrior.The original French names for the main characters are the following: The character names can either be the original French names or the English translations, though many countries have also adapted separate local translations. Of course, in the videogame, Asterix and Obelix are not invincible anymore but simply very strong - or else, there wouldn't be much of a challenge. Obelix is so strong because he fell into the magic potion's brewing pot while he was a little child, which made him permanently invincible. Truth is: none of the two heroes is ever wounded in any way during the entire series. In the original French series, this 'magic potion' makes the people who drink it invincible - that what's stated in the first comics anyway, though things are not so clear anymore in 'Asterix and the laurel wreath', where Asterix claims that 'the magic potion makes very strong but not invulnerable'. The games revolve around the heroic adventures of Asterix and his sidekick Obelix, the menhir delivery man assisted by the valiant Dogmatix, his dog protecting the only Gaulish village (with no name and located in the northwest corner of Gaul) unconquered by Roman conquest under Julius Caesar, with the help of the 'magic potion' brewed by the village druid, Getafix. Asterix and Obelix licensees Group DescriptionGames based on the French comic series written by René Goscinny and written and illustrated by Albert Uderzo, featuring the fictional Gaulish warrior Asterix, introduced in 1959 as Astérix le Gaulois (Asterix the Gaul). ![]() ![]() ![]() So, with just a few seconds of work, we now have a finished image, ready for print or web output. Here, I adjusted the basic tone and presence sliders, along with a small tweak to the white balance. With the preset laying the foundation, we can now fine-tune the image to its finished treatment. Leica SL (Typ 601) image with my preset applied We could stop here, but really, this is just a starting point. All of the correct sharpening and basic toning is set. Now, let's see what happens when I simply apply my SL601 preset. Leica SL (Typ 601) image with default settings in Lightroom Clearly, the exposure is correct and the white balance seems decent enough, but the image is flat. Some might call this out of camera, but that's not an accurate description as we already discussed. Let's start with the default Lightroom treatment of an SL (Typ 601) shot I took in Iceland this past August. For challenging, high contrast images, you might have to dive into local adjustments like the Gradient tool or the Local Adjustment Brush, but at least you’ll have a solid foundation of enhancements to build off. After that, usually small adjustments to the highlight and shadow slider will get most images looking good. So, before anything else, you’ll want to get these basic settings dialed in. Also, the preset will not adjust exposure or white balance. Every image is unique and as such will require individual attention. And this is because a lot of the base adjustments are similar. For my first Leica CL images, I turned to the TL2 for guidance. When the SL2 came out, I started with my SL (Typ 601) preset as a starting point. There’s no magic here, just a set of saved adjustments.Īs I start using a new camera model, I will generally adapt a previous preset from a similar camera. Past that, if I see some color weirdness, I might input small tweaks in the HSL/Color (Hue/Saturation/Lightness) panel. At a bare minimum, we’re talking about camera profile, sharpening, lens corrections, basic tone and presence. My goal is to offload the settings that I always change, for every image, for a given camera. Leica S (Typ 007) with 45mm Elmarit-S ASPH What’s in the presets? Not out of camera, but rather the best version of reality Just like in cooking, sometimes “just a pinch” is all you need to elevate the final product. With digital capture and the ever-improving capabilities of the sensors, the possibilities for post processing are almost limitless. And truthfully, this balancing act isn’t always easy. My goal is to create what I refer to as “the best version of reality.” Look, I don’t want a flat and dull image, nor do I care for an over-processed, artificial-looking mess. The desired result isn’t necessarily accurate but is pleasing to my eye. And honestly, I don’t think it matters anyway.įor my own workflow, I’ve created presets for each Leica camera that I shoot with. The default rendering of an image depends on a multitude of variables, like how a program handles the de-Bayering algorithm, which camera profile is used, and whatever default adjustments Lightroom pre-applies. If you shoot in any RAW format, be it DNG for Leica files, or otherwise, OOC simply doesn’t exist. There is no such thing as “Out of Camera,” unless you are shooting JPG. But aren’t Leica files out of camera amazing? Why would I need to change anything? ![]() Also, older non-CC standalone versions may not work with the newer XML file type. I have not tested them with Lightroom CC, which is more of a light version, or with Lightroom Mobile. Now before we get too far along, I do want to clarify that these presets are designed to work with Adobe Lightroom Classic CC, which is the latest version. Ultimately, incorporating presets into your Lightroom workflow can be a massive time saver. This makes the selecting and editing process much more streamlined and efficient. And while the main advantage is to offload all the repetitive work for you, a notable and welcome benefit is that once imported, all the images will have your preferred treatment, even before touching a single slider. Or, if you want to harness their true power, have Lightroom automatically apply to all files during the Import process. ![]() When you select a preset in the Develop module, this recipe of adjustments will be applied to a single file. They are simply a saved set of instructions, a recipe of sorts. I’ve taken advantage of Develop Presets when importing and processing my Leica DNG files since switching to Adobe Lightroom in 2009. ![]() ![]() ![]() Honda (Jack-X's swap costume), El Furte (Marshall Law's swap costume), Geki (Lars' swap costume), Gill (Ogre's swap costume), juli (Christie's swap costume), Rainbow Mika (Kuma's swap costume), Urien (Bryan's swap costume). Street Fighter: Alex (King's swap costume), Charlie Nash (Steve's swap costume), C.Viper (Jin's swap costume), Dan Hibiki (Lei's swap costume), Dee Jay (Hwoarang's swap costume), E. While all playable characters are featured as someone else' Swap Costume, there are also a number of them based on characters not in the roster. "Swap Costumes" are special costumes which sees a character from one series dressing like a character from the other.
![]() However, newer coins, like the Kennedy Silver Dollar, need to be in excellent physical condition to retain collectors’ value. Examples of rare coins include the Kennedy Silver Half Dollars and the Morgan or Peace Dollars.X Research source Grading takes into account how well the coin was struck at the original mint, how well it is preserved, and how much wear and damage the coin has suffered. Territories: 2003-S Missouri Silver 2006-S Colorado 2008-S Hawaii Silver Proof Only Issues 2003-S. 2003-S Missouri 2006-S Nebraska Silver 2008-S Hawaii & U.S. You must also pay attention to coin grading, which how you determine the quality of a coin's condition. P a g e 20 The Complete Checklist of United States Coins 2003-S Maine 2006-S Nevada Silver 2008-S Alaska 2003-S Maine Silver 2006-S Nebraska 2008-S Alaska Silver Washington, D.C.X Research source A coin may have been produced in mass quantities at one mint, but in much smaller quantities at another mint if your coin came from the latter, it will be worth more. The mint refers to where the coin was produced and is denoted by a small letter stamped on the coin. Other coins garner a collector’s value because they are a rare mint.In general, coins that pre-date the 1940s have some collectors’ value.Search online for the value of your coin by referencing the date and image on the coin. However, rare coins accumulate additional value. ![]() The majority of junk silver is valued almost exclusively by its silver content. Confirm that your junk silver coins have no numismatic value. ![]() ![]() ![]() See No Evil 2006 DvDrip AC3 Eng aXXo, keith owen favorite moves. ![]() quick heal total security 2012 keygen free download serial Ms Buchhalter Bilanz 3 22 Serial Warrior 2011 VODRiP XviD SiC Autodesk Inventor Suite Professional 2010 x 86 crack Gantt OCX v1 22 свое launcher pro plus 0 8 3 apk mediafire. Grease Fullscreen mp4, La Traviata Verdi Zeffirelli Teresa Stratas,Placido Doming avira antivirus 2012 license key file serial, Comanche 4 download epc bronze serial key keygen the speckerman recurrence registryreviver. serial crack key speedupmypc 2012 crack download epc bronze serial key keygen solidworks 2011 free download from rapidshare keygen hansi The Book Of Css3 A Developers Guide To The Future Of Web Design Pdf watch pishin karbala scandel download epc bronze serial key keygen Keygen adobe indesign cs4 serial number. jaheim, Il Teatro Degli Orrori A Sangue Freddo 2009. Kyou Kara Maou 01 78 complete video convert master 7 9 5 1, Crack Steinberg WaveLab LE v7 1 1 Dream House 2011 DVDRip XviD EMBER snehituda mp3, MICROSOFT OFFICE 2010 RTM EDITION VOLUME X86 X64 DVD ENGLISH activation key for avg antivirus 2012 keygen download epc bronze serial key keygen. If you have this page bookmarked, please update your favorites Please click on the link below to go to the new page: Sorry, the page you requested has been moved. ![]() |
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